Arsenal vs PSV Predictions, 66/1 Bet Builder and Betting Tips

Last Updated on 16/08/2025 by Andy Clark

Arsenal vs PSV bet builder tips for Wednesday’s fixture in the Champions League with a team to win, player to have a shot on target and two players to be carded in the match. Betting odds

• Arsenal are 2/5 favourites for the win at home
• The draw is 4/1
• A win on the road for PSV is 6/1

Arsenal hammered PSV 1-7 in the first leg, so this tie is all but over. The Gunners are 6/1 to win the Champions League. PSV are effectively out of the competition already, and they are longest odds of all at 2500/1 to win the competition.  

Arsenal vs PSV Bet Builder Tip

• Arsenal to win
• Leandro Trossard one or more shot on target
• Declan Rice to be booked
• Ivan Perisic to be booked

Betting odds: 66/1 with bet365.

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Arsenal vs PSV Predictions

As previously mentioned, Arsenal hammered PSV on their own patch in Holland last week, with a massive 1-7 scoreline. I’m backing the Gunners to win again here in front of their home support. Following last week’s beating, I don’t think PSV will have the confidence to overcome Arsenal, and I think it could be another dominant display from Mikel Arteta’s side. PSV have won only three of their last 10 in the league, so are in poor form overall, while Arsenal are unbeaten in eight of their last 10 in all competitions. I’ve gone for Leandro Trossard to have one or more shots on target here. He has six goals to his name so far this season, four in the league and two in his nine Champions League appearances. In the league, he has had 14 shots on target in 28 appearances, an average of 0.5 per game. I think Arsenal will create a lot of chances here, and Trossard is good odds for one or more shot on target. We’ve chosen two players to be booked, boosting this bet builder to a solid 66/1 with Bet365. Declan Rice is the first of the two. He has been carded five times this season, four times in the league and once in the Champions League. He averages over 0.5 fouls per game, and while PSV look to avoid another embarrassment, it’ll be a tough battle in the middle of the park. We’ve also gone for PSV’s Ivan Perisic to be booked. The former Spurs man will be keen to make an impression on his return to London. He has been carded five times this season – three times in the league and twice in the KNVB Cup. I think he’s also good odds to pick up another booking here.  

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